Cargando…
Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
We report the first class of stable, two-dimensional (2D) anti-ferromagnetically coupled dendritic polyradicaloids. A kinetically blocked fluorenyl radical was used to build up the first and second generation dendrons FR-G1 and FR-G2 containing three and seven fluorenyl units, respectively. The neig...
Autores principales: | , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933225/ https://www.ncbi.nlm.nih.gov/pubmed/29780470 http://dx.doi.org/10.1039/c7sc05493a |
_version_ | 1783319937974009856 |
---|---|
author | Wang, Jian Kim, Gakhyun Sandoval-Salinas, María Eugenia Phan, Hoa Gopalakrishna, Tullimilli Y. Lu, Xuefeng Casanova, David Kim, Dongho Wu, Jishan |
author_facet | Wang, Jian Kim, Gakhyun Sandoval-Salinas, María Eugenia Phan, Hoa Gopalakrishna, Tullimilli Y. Lu, Xuefeng Casanova, David Kim, Dongho Wu, Jishan |
author_sort | Wang, Jian |
collection | PubMed |
description | We report the first class of stable, two-dimensional (2D) anti-ferromagnetically coupled dendritic polyradicaloids. A kinetically blocked fluorenyl radical was used to build up the first and second generation dendrons FR-G1 and FR-G2 containing three and seven fluorenyl units, respectively. The neighboring fluorenyl radicals in FR-G1 and FR-G2 show moderate anti-ferromagnetic exchange interaction, resulting in a doublet and quartet ground state, respectively, with a small doublet–quartet energy gap. From FR-G1 to FR-G2, the energy gap decreased and the two-photon absorption was enhanced owing to more extended 2D π-conjugation. Both compounds showed multiple redox waves due to their polyradical character. |
format | Online Article Text |
id | pubmed-5933225 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-59332252018-05-18 Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons Wang, Jian Kim, Gakhyun Sandoval-Salinas, María Eugenia Phan, Hoa Gopalakrishna, Tullimilli Y. Lu, Xuefeng Casanova, David Kim, Dongho Wu, Jishan Chem Sci Chemistry We report the first class of stable, two-dimensional (2D) anti-ferromagnetically coupled dendritic polyradicaloids. A kinetically blocked fluorenyl radical was used to build up the first and second generation dendrons FR-G1 and FR-G2 containing three and seven fluorenyl units, respectively. The neighboring fluorenyl radicals in FR-G1 and FR-G2 show moderate anti-ferromagnetic exchange interaction, resulting in a doublet and quartet ground state, respectively, with a small doublet–quartet energy gap. From FR-G1 to FR-G2, the energy gap decreased and the two-photon absorption was enhanced owing to more extended 2D π-conjugation. Both compounds showed multiple redox waves due to their polyradical character. Royal Society of Chemistry 2018-02-28 /pmc/articles/PMC5933225/ /pubmed/29780470 http://dx.doi.org/10.1039/c7sc05493a Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0) |
spellingShingle | Chemistry Wang, Jian Kim, Gakhyun Sandoval-Salinas, María Eugenia Phan, Hoa Gopalakrishna, Tullimilli Y. Lu, Xuefeng Casanova, David Kim, Dongho Wu, Jishan Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons |
title | Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
|
title_full | Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
|
title_fullStr | Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
|
title_full_unstemmed | Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
|
title_short | Stable 2D anti-ferromagnetically coupled fluorenyl radical dendrons
|
title_sort | stable 2d anti-ferromagnetically coupled fluorenyl radical dendrons |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5933225/ https://www.ncbi.nlm.nih.gov/pubmed/29780470 http://dx.doi.org/10.1039/c7sc05493a |
work_keys_str_mv | AT wangjian stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT kimgakhyun stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT sandovalsalinasmariaeugenia stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT phanhoa stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT gopalakrishnatullimilliy stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT luxuefeng stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT casanovadavid stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT kimdongho stable2dantiferromagneticallycoupledfluorenylradicaldendrons AT wujishan stable2dantiferromagneticallycoupledfluorenylradicaldendrons |