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Chemical shift extremum of (129)Xe(aq) reveals details of hydrophobic solvation
The (129)Xe chemical shift in an aqueous solution exhibits a non-monotonic temperature dependence, featuring a maximum at 311 K. This is in contrast to most liquids, where the monotonic decrease of the shift follows that of liquid density. In particular, the shift maximum in water occurs at a higher...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5935698/ https://www.ncbi.nlm.nih.gov/pubmed/29728689 http://dx.doi.org/10.1038/s41598-018-25418-4 |