Spectroscopic investigations of a semi-synthetic [FeFe] hydrogenase with propane di-selenol as bridging ligand in the binuclear subsite: comparison to the wild type and propane di-thiol variants

[FeFe] Hydrogenases catalyze the reversible conversion of H(2) into electrons and protons. Their catalytic site, the H-cluster, contains a generic [4Fe–4S](H) cluster coupled to a [2Fe](H) subsite [Fe(2)(ADT)(CO)(3)(CN)(2)](2−), ADT = µ(SCH(2))(2)NH. Heterologously expressed [FeFe] hydrogenases (apo...

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Detalles Bibliográficos
Autores principales: Sommer, C., Rumpel, S., Roy, S., Farès, C., Artero, V., Fontecave, M., Reijerse, E., Lubitz, W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2018
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5940705/
https://www.ncbi.nlm.nih.gov/pubmed/29627860
http://dx.doi.org/10.1007/s00775-018-1558-4

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