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Pressurized CO(2) as a carboxylating agent for the biocatalytic ortho-carboxylation of resorcinol
The utilization of gaseous carbon dioxide instead of bicarbonate would greatly facilitate process development for enzyme catalyzed carboxylations on a large scale. As a proof-of-concept, 1,3-dihydroxybenzene (resorcinol) was carboxylated in the ortho-position using pressurized CO(2) (∼30–40 bar) cat...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5942041/ https://www.ncbi.nlm.nih.gov/pubmed/29780282 http://dx.doi.org/10.1039/c8gc00008e |