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An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state
The iridium(iii/iv/v) imido redox series [Ir(NtBu){N(CHCHPtBu(2))(2)}](0/+/2+) was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium(iv) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character a...
| Autores principales: | , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944377/ https://www.ncbi.nlm.nih.gov/pubmed/29780564 http://dx.doi.org/10.1039/c8sc01113c |