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Spontaneous formation of a chiral (Mo(2)O(2)S(2))(2+)-based cluster driven by dimeric {Te(2)O(6)}-based templates
Utilization of [Mo(2)S(2)O(2)(H(2)O)(6)](2+) and a tellurite anion led to the formation of three new clusters, 1–3, with unique structural features. The tellurite anion not only templated the formation of [(Mo(2)O(2)S(2))(4)(TeO(3))(OH)(9)](3–)1 and [(Mo(2)O(2)S(2))(12)(TeO(3))(4)(TeO(4))(2) (OH)(18...
Autores principales: | Purcell, Jamie W., Long, De-Liang, Lee, Edward C., Cronin, Leroy, Miras, Haralampos N. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944425/ https://www.ncbi.nlm.nih.gov/pubmed/29667663 http://dx.doi.org/10.1039/c8dt00832a |
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