C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex

The photochemical oxidation of a (TAML)Fe(III) complex 1 using visible light generated Ru(bpy)(3)(3+) produces valence tautomers (TAML)Fe(IV) (1(+)) and (TAML˙(+))Fe(III) (1-TAML˙(+)), depending on the exogenous anions. The presence of labile Cl(–) or Br(–) results in a ligand-based oxidation and st...

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Detalles Bibliográficos
Autores principales: Lim, Jia Hui, Engelmann, Xenia, Corby, Sacha, Ganguly, Rakesh, Ray, Kallol, Soo, Han Sen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944818/
https://www.ncbi.nlm.nih.gov/pubmed/29862004
http://dx.doi.org/10.1039/c7sc05378a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5944818/
https://www.ncbi.nlm.nih.gov/pubmed/29862004
http://dx.doi.org/10.1039/c7sc05378a

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