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BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties
A series of D–A dyads and D–A–D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have bee...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer International Publishing
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5945575/ https://www.ncbi.nlm.nih.gov/pubmed/29748728 http://dx.doi.org/10.1186/s13065-018-0430-5 |
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author | Wanwong, Sompit Khomein, Piyachai Thayumanavan, S. |
author_facet | Wanwong, Sompit Khomein, Piyachai Thayumanavan, S. |
author_sort | Wanwong, Sompit |
collection | PubMed |
description | A series of D–A dyads and D–A–D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have been investigated. We found that the D–A–D triads exhibited broader absorption, raising the HOMO energy levels and increase hole carrier mobilities. Analysis surface morphology revealed that BODIPY containing carbazole demonstrated smooth film and no macro phase aggregation was observed upon thermal annealing. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1186/s13065-018-0430-5) contains supplementary material, which is available to authorized users. |
format | Online Article Text |
id | pubmed-5945575 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Springer International Publishing |
record_format | MEDLINE/PubMed |
spelling | pubmed-59455752018-05-14 BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties Wanwong, Sompit Khomein, Piyachai Thayumanavan, S. Chem Cent J Research Article A series of D–A dyads and D–A–D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have been investigated. We found that the D–A–D triads exhibited broader absorption, raising the HOMO energy levels and increase hole carrier mobilities. Analysis surface morphology revealed that BODIPY containing carbazole demonstrated smooth film and no macro phase aggregation was observed upon thermal annealing. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1186/s13065-018-0430-5) contains supplementary material, which is available to authorized users. Springer International Publishing 2018-05-11 /pmc/articles/PMC5945575/ /pubmed/29748728 http://dx.doi.org/10.1186/s13065-018-0430-5 Text en © The Author(s) 2018 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated. |
spellingShingle | Research Article Wanwong, Sompit Khomein, Piyachai Thayumanavan, S. BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title | BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title_full | BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title_fullStr | BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title_full_unstemmed | BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title_short | BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties |
title_sort | bodipy dyads and triads: synthesis, optical, electrochemical and transistor properties |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5945575/ https://www.ncbi.nlm.nih.gov/pubmed/29748728 http://dx.doi.org/10.1186/s13065-018-0430-5 |
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