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Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate

In the title compound, C(17)H(15)N(3)O(3), the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azo­benzene segment, which adopts a configuration close to planar. In the crystal, mol­ecules are oriented pairwise by (2-oxopyrrolidin-3-yl)­oxy moieties at an angle of...

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Detalles Bibliográficos
Autores principales: Elkin, Igor, Maris, Thierry, Melkoumov, Alexandre, Hildgen, Patrice, Banquy, Xavier, Leclair, Grégoire, Barrett, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946967/
https://www.ncbi.nlm.nih.gov/pubmed/29765745
http://dx.doi.org/10.1107/S205698901800333X
Descripción
Sumario:In the title compound, C(17)H(15)N(3)O(3), the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azo­benzene segment, which adopts a configuration close to planar. In the crystal, mol­ecules are oriented pairwise by (2-oxopyrrolidin-3-yl)­oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking inter­actions, forming zigzag supra­molecular chains parallel to [010] further linked via additional C—H⋯π inter­actions.