Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate

In the title compound, C(17)H(15)N(3)O(3), the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azo­benzene segment, which adopts a configuration close to planar. In the crystal, mol­ecules are oriented pairwise by (2-oxopyrrolidin-3-yl)­oxy moieties at an angle of...

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Autores principales: Elkin, Igor, Maris, Thierry, Melkoumov, Alexandre, Hildgen, Patrice, Banquy, Xavier, Leclair, Grégoire, Barrett, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946967/
https://www.ncbi.nlm.nih.gov/pubmed/29765745
http://dx.doi.org/10.1107/S205698901800333X
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author Elkin, Igor
Maris, Thierry
Melkoumov, Alexandre
Hildgen, Patrice
Banquy, Xavier
Leclair, Grégoire
Barrett, Christopher
author_facet Elkin, Igor
Maris, Thierry
Melkoumov, Alexandre
Hildgen, Patrice
Banquy, Xavier
Leclair, Grégoire
Barrett, Christopher
author_sort Elkin, Igor
collection PubMed
description In the title compound, C(17)H(15)N(3)O(3), the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azo­benzene segment, which adopts a configuration close to planar. In the crystal, mol­ecules are oriented pairwise by (2-oxopyrrolidin-3-yl)­oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking inter­actions, forming zigzag supra­molecular chains parallel to [010] further linked via additional C—H⋯π inter­actions.
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spelling pubmed-59469672018-05-15 Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate Elkin, Igor Maris, Thierry Melkoumov, Alexandre Hildgen, Patrice Banquy, Xavier Leclair, Grégoire Barrett, Christopher Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(17)H(15)N(3)O(3), the plane of the pyrrolidone ring is inclined at an angle of 59.791 (2)° to that of the azo­benzene segment, which adopts a configuration close to planar. In the crystal, mol­ecules are oriented pairwise by (2-oxopyrrolidin-3-yl)­oxy moieties at an angle of 76.257 (3)°, linked by hydrogen bonds and π-stacking inter­actions, forming zigzag supra­molecular chains parallel to [010] further linked via additional C—H⋯π inter­actions. International Union of Crystallography 2018-03-06 /pmc/articles/PMC5946967/ /pubmed/29765745 http://dx.doi.org/10.1107/S205698901800333X Text en © Elkin et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Elkin, Igor
Maris, Thierry
Melkoumov, Alexandre
Hildgen, Patrice
Banquy, Xavier
Leclair, Grégoire
Barrett, Christopher
Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title_full Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title_fullStr Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title_full_unstemmed Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title_short Crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
title_sort crystal structure of 2-oxopyrrolidin-3-yl 4-(2-phenyl­diazen-1-yl)benzoate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946967/
https://www.ncbi.nlm.nih.gov/pubmed/29765745
http://dx.doi.org/10.1107/S205698901800333X
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