Crystal structure of bis­(diiso­propyl­ammonium) cis-di­iodido­bis­(oxolato-κ(2) O (1),O (2))stannate(IV)

In the title compound, ((i)Pr(2)NH(2))(2)[SnI(2)(C(2)O(4))(2)], which was prepared by reacting ((i)Pr(2)NH(2) (+))(2)·C(2)O(4) (2−) with SnI(4) in a 2:1 molar ratio in a mixed ethanol–aceto­nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter...

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Detalles Bibliográficos
Autores principales: Sarr, Bougar, Diop, Cheikh Abdoul Khadir, Sidibé, Mamadou, Rousselin, Yoann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946977/
https://www.ncbi.nlm.nih.gov/pubmed/29765755
http://dx.doi.org/10.1107/S2056989018003602
Descripción
Sumario:In the title compound, ((i)Pr(2)NH(2))(2)[SnI(2)(C(2)O(4))(2)], which was prepared by reacting ((i)Pr(2)NH(2) (+))(2)·C(2)O(4) (2−) with SnI(4) in a 2:1 molar ratio in a mixed ethanol–aceto­nitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H⋯O and bifurcated N—H⋯(O,O) hydrogen bonds, generating [10-1] chains.

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