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Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2) O (1),O (2))stannate(IV)
In the title compound, ((i)Pr(2)NH(2))(2)[SnI(2)(C(2)O(4))(2)], which was prepared by reacting ((i)Pr(2)NH(2) (+))(2)·C(2)O(4) (2−) with SnI(4) in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946977/ https://www.ncbi.nlm.nih.gov/pubmed/29765755 http://dx.doi.org/10.1107/S2056989018003602 |
| _version_ | 1783322278649397248 |
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| author | Sarr, Bougar Diop, Cheikh Abdoul Khadir Sidibé, Mamadou Rousselin, Yoann |
| author_facet | Sarr, Bougar Diop, Cheikh Abdoul Khadir Sidibé, Mamadou Rousselin, Yoann |
| author_sort | Sarr, Bougar |
| collection | PubMed |
| description | In the title compound, ((i)Pr(2)NH(2))(2)[SnI(2)(C(2)O(4))(2)], which was prepared by reacting ((i)Pr(2)NH(2) (+))(2)·C(2)O(4) (2−) with SnI(4) in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H⋯O and bifurcated N—H⋯(O,O) hydrogen bonds, generating [10-1] chains. |
| format | Online Article Text |
| id | pubmed-5946977 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-59469772018-05-15 Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2) O (1),O (2))stannate(IV) Sarr, Bougar Diop, Cheikh Abdoul Khadir Sidibé, Mamadou Rousselin, Yoann Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, ((i)Pr(2)NH(2))(2)[SnI(2)(C(2)O(4))(2)], which was prepared by reacting ((i)Pr(2)NH(2) (+))(2)·C(2)O(4) (2−) with SnI(4) in a 2:1 molar ratio in a mixed ethanol–acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N—H⋯O and bifurcated N—H⋯(O,O) hydrogen bonds, generating [10-1] chains. International Union of Crystallography 2018-03-09 /pmc/articles/PMC5946977/ /pubmed/29765755 http://dx.doi.org/10.1107/S2056989018003602 Text en © Sarr et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Sarr, Bougar Diop, Cheikh Abdoul Khadir Sidibé, Mamadou Rousselin, Yoann Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2) O (1),O (2))stannate(IV) |
| title | Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
O
(1),O
(2))stannate(IV) |
| title_full | Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
O
(1),O
(2))stannate(IV) |
| title_fullStr | Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
O
(1),O
(2))stannate(IV) |
| title_full_unstemmed | Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
O
(1),O
(2))stannate(IV) |
| title_short | Crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
O
(1),O
(2))stannate(IV) |
| title_sort | crystal structure of bis(diisopropylammonium) cis-diiodidobis(oxolato-κ(2)
o
(1),o
(2))stannate(iv) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946977/ https://www.ncbi.nlm.nih.gov/pubmed/29765755 http://dx.doi.org/10.1107/S2056989018003602 |
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