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Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-trimethoxydiphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −1...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946980/ https://www.ncbi.nlm.nih.gov/pubmed/29765758 http://dx.doi.org/10.1107/S2056989018003717 |
Sumario: | In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-trimethoxydiphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −123.62 (12) and −115.54 (12)°. A possible weak intramolecular C—H⋯O interaction is observed. In the crystal, molecules are connected by two C—H⋯O hydrogen bonds, forming undulating layers lying parallel to the bc plane. Weak C—H⋯π and π–π stacking interactions also occur. |
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