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Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)

In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-tri­meth­oxy­diphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −1...

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Autores principales: Grecco, Simone S., Jerz, Gerold, Lago, Joao Henrique G., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946980/
https://www.ncbi.nlm.nih.gov/pubmed/29765758
http://dx.doi.org/10.1107/S2056989018003717
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author Grecco, Simone S.
Jerz, Gerold
Lago, Joao Henrique G.
Jones, Peter G.
author_facet Grecco, Simone S.
Jerz, Gerold
Lago, Joao Henrique G.
Jones, Peter G.
author_sort Grecco, Simone S.
collection PubMed
description In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-tri­meth­oxy­diphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −123.62 (12) and −115.54 (12)°. A possible weak intra­molecular C—H⋯O inter­action is observed. In the crystal, mol­ecules are connected by two C—H⋯O hydrogen bonds, forming undulating layers lying parallel to the bc plane. Weak C—H⋯π and π–π stacking inter­actions also occur.
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spelling pubmed-59469802018-05-15 Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) Grecco, Simone S. Jerz, Gerold Lago, Joao Henrique G. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-tri­meth­oxy­diphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −123.62 (12) and −115.54 (12)°. A possible weak intra­molecular C—H⋯O inter­action is observed. In the crystal, mol­ecules are connected by two C—H⋯O hydrogen bonds, forming undulating layers lying parallel to the bc plane. Weak C—H⋯π and π–π stacking inter­actions also occur. International Union of Crystallography 2018-03-09 /pmc/articles/PMC5946980/ /pubmed/29765758 http://dx.doi.org/10.1107/S2056989018003717 Text en © Grecco et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Grecco, Simone S.
Jerz, Gerold
Lago, Joao Henrique G.
Jones, Peter G.
Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title_full Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title_fullStr Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title_full_unstemmed Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title_short Crystal structure of De­hydro­dieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
title_sort crystal structure of de­hydro­dieugenol b methyl ether, a neolignan from nectandra leucantha nees and mart (lauraceae)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946980/
https://www.ncbi.nlm.nih.gov/pubmed/29765758
http://dx.doi.org/10.1107/S2056989018003717
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