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Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae)
In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-trimethoxydiphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −1...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946980/ https://www.ncbi.nlm.nih.gov/pubmed/29765758 http://dx.doi.org/10.1107/S2056989018003717 |
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author | Grecco, Simone S. Jerz, Gerold Lago, Joao Henrique G. Jones, Peter G. |
author_facet | Grecco, Simone S. Jerz, Gerold Lago, Joao Henrique G. Jones, Peter G. |
author_sort | Grecco, Simone S. |
collection | PubMed |
description | In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-trimethoxydiphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −123.62 (12) and −115.54 (12)°. A possible weak intramolecular C—H⋯O interaction is observed. In the crystal, molecules are connected by two C—H⋯O hydrogen bonds, forming undulating layers lying parallel to the bc plane. Weak C—H⋯π and π–π stacking interactions also occur. |
format | Online Article Text |
id | pubmed-5946980 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-59469802018-05-15 Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) Grecco, Simone S. Jerz, Gerold Lago, Joao Henrique G. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(21)H(24)O(4) (systematic name: 4,5′-diallyl-2,2′,3′-trimethoxydiphenyl ether), the aromatic rings lie almost perpendicular to each other [dihedral angle = 85.96 (2)°]. The allyl side chains show similar configurations, with C(ar)—C—C=C (ar = aromatic) torsion angles of −123.62 (12) and −115.54 (12)°. A possible weak intramolecular C—H⋯O interaction is observed. In the crystal, molecules are connected by two C—H⋯O hydrogen bonds, forming undulating layers lying parallel to the bc plane. Weak C—H⋯π and π–π stacking interactions also occur. International Union of Crystallography 2018-03-09 /pmc/articles/PMC5946980/ /pubmed/29765758 http://dx.doi.org/10.1107/S2056989018003717 Text en © Grecco et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Grecco, Simone S. Jerz, Gerold Lago, Joao Henrique G. Jones, Peter G. Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title | Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title_full | Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title_fullStr | Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title_full_unstemmed | Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title_short | Crystal structure of Dehydrodieugenol B methyl ether, a neolignan from Nectandra leucantha Nees and Mart (Lauraceae) |
title_sort | crystal structure of dehydrodieugenol b methyl ether, a neolignan from nectandra leucantha nees and mart (lauraceae) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946980/ https://www.ncbi.nlm.nih.gov/pubmed/29765758 http://dx.doi.org/10.1107/S2056989018003717 |
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