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Synthesis and crystallographic characterization of [2,2-bis(η(5)-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO (5)]triisobutylaluminium

The crystal structure of the title zwitterionic zirconocene complex containing a furanone unit, [AlZr(C(10)H(15))(2)(C(4)H(9))(3)(C(9)H(18)O(2)Si(2))], is reported. On reacting a zirconafuranone with two equivalents of HAl(i-Bu)(2), disproportionation of the Lewis acid results in the formation of...

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Detalles Bibliográficos
Autores principales:	Burlakov, Vladimir V., Bogdanov, Vyacheslav S., Arndt, Perdita, Spannenberg, Anke, Rosenthal, Uwe, Beweries, Torsten, Shur, Vladimir B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2018
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5946991/ https://www.ncbi.nlm.nih.gov/pubmed/29765769 http://dx.doi.org/10.1107/S2056989018004759

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