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Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
The title compound, [Fe(2)(C(5)H(5))(2)(C(20)H(14)O(2))], is the product of a new synthetic route towards tetraaryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the molecule is centrosymmetric and the cyclopentadienyl (Cp) rings are nearly coplanar an...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947475/ https://www.ncbi.nlm.nih.gov/pubmed/29850079 http://dx.doi.org/10.1107/S2056989018005078 |
Sumario: | The title compound, [Fe(2)(C(5)H(5))(2)(C(20)H(14)O(2))], is the product of a new synthetic route towards tetraaryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the molecule is centrosymmetric and the cyclopentadienyl (Cp) rings are nearly coplanar and aligned slightly closer to a staggered conformation than to an eclipsed one. The ethene plane is tilted by 32.40 (18)° with respect to that of the substituted Cp ring and by 63.19 (19)° with respect to that of the furan ring. C—H⋯π interactions link the molecules into a three-dimensional supramolecular framework. |
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