Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene

The title compound, [Fe(2)(C(5)H(5))(2)(C(20)H(14)O(2))], is the product of a new synthetic route towards tetra­aryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the mol­ecule is centrosymmetric and the cyclo­penta­dienyl (Cp) rings are nearly coplanar an...

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Autores principales: Linden, Anthony, Hamera-Fałdyga, Róża, Mlostoń, Grzegorz, Heimgartner, Heinz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947475/
https://www.ncbi.nlm.nih.gov/pubmed/29850079
http://dx.doi.org/10.1107/S2056989018005078
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author Linden, Anthony
Hamera-Fałdyga, Róża
Mlostoń, Grzegorz
Heimgartner, Heinz
author_facet Linden, Anthony
Hamera-Fałdyga, Róża
Mlostoń, Grzegorz
Heimgartner, Heinz
author_sort Linden, Anthony
collection PubMed
description The title compound, [Fe(2)(C(5)H(5))(2)(C(20)H(14)O(2))], is the product of a new synthetic route towards tetra­aryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the mol­ecule is centrosymmetric and the cyclo­penta­dienyl (Cp) rings are nearly coplanar and aligned slightly closer to a staggered conformation than to an eclipsed one. The ethene plane is tilted by 32.40 (18)° with respect to that of the substituted Cp ring and by 63.19 (19)° with respect to that of the furan ring. C—H⋯π inter­actions link the mol­ecules into a three-dimensional supramolecular framework.
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spelling pubmed-59474752018-05-30 Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene Linden, Anthony Hamera-Fałdyga, Róża Mlostoń, Grzegorz Heimgartner, Heinz Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Fe(2)(C(5)H(5))(2)(C(20)H(14)O(2))], is the product of a new synthetic route towards tetra­aryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the mol­ecule is centrosymmetric and the cyclo­penta­dienyl (Cp) rings are nearly coplanar and aligned slightly closer to a staggered conformation than to an eclipsed one. The ethene plane is tilted by 32.40 (18)° with respect to that of the substituted Cp ring and by 63.19 (19)° with respect to that of the furan ring. C—H⋯π inter­actions link the mol­ecules into a three-dimensional supramolecular framework. International Union of Crystallography 2018-04-06 /pmc/articles/PMC5947475/ /pubmed/29850079 http://dx.doi.org/10.1107/S2056989018005078 Text en © Linden et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Linden, Anthony
Hamera-Fałdyga, Róża
Mlostoń, Grzegorz
Heimgartner, Heinz
Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title_full Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title_fullStr Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title_full_unstemmed Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title_short Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
title_sort crystal structure of (e)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947475/
https://www.ncbi.nlm.nih.gov/pubmed/29850079
http://dx.doi.org/10.1107/S2056989018005078
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