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Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)

The crystal and mol­ecular structures of two tri­phenyl­tin di­thio­carbamate compounds, viz. [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], (I), and [Sn(C(6)H(5))(3)(C(10)H(12)NS(2))], (II), are described. The di­thio­carbamate ligand in each mol­ecule coordinates in an asymmetric fashion resulting in heavily...

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Autores principales: Mohamad, Rapidah, Awang, Normah, Kamaludin, Nurul Farahana, Jotani, Mukesh M., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947476/
https://www.ncbi.nlm.nih.gov/pubmed/29850080
http://dx.doi.org/10.1107/S2056989018005133
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author Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul Farahana
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_facet Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul Farahana
Jotani, Mukesh M.
Tiekink, Edward R. T.
author_sort Mohamad, Rapidah
collection PubMed
description The crystal and mol­ecular structures of two tri­phenyl­tin di­thio­carbamate compounds, viz. [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], (I), and [Sn(C(6)H(5))(3)(C(10)H(12)NS(2))], (II), are described. The di­thio­carbamate ligand in each mol­ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra­hedral C(3)S coordin­ation geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The mol­ecular packing in both compounds features C—H⋯π(Sn-phen­yl) inter­actions. In (I), the donors are Sn-phenyl-C—H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C—H and methyl-C—H groups leading to supra­molecular chains propagating along the b axis. The identified aggregates assemble into their respective crystals with no directional inter­actions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (>99% in each case) of H⋯H, C⋯H/H⋯C and S⋯H/H⋯S contacts on the respective Hirshfeld surface.
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spelling pubmed-59474762018-05-30 Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV) Mohamad, Rapidah Awang, Normah Kamaludin, Nurul Farahana Jotani, Mukesh M. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The crystal and mol­ecular structures of two tri­phenyl­tin di­thio­carbamate compounds, viz. [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], (I), and [Sn(C(6)H(5))(3)(C(10)H(12)NS(2))], (II), are described. The di­thio­carbamate ligand in each mol­ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra­hedral C(3)S coordin­ation geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The mol­ecular packing in both compounds features C—H⋯π(Sn-phen­yl) inter­actions. In (I), the donors are Sn-phenyl-C—H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C—H and methyl-C—H groups leading to supra­molecular chains propagating along the b axis. The identified aggregates assemble into their respective crystals with no directional inter­actions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (>99% in each case) of H⋯H, C⋯H/H⋯C and S⋯H/H⋯S contacts on the respective Hirshfeld surface. International Union of Crystallography 2018-04-06 /pmc/articles/PMC5947476/ /pubmed/29850080 http://dx.doi.org/10.1107/S2056989018005133 Text en © Mohamad et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Mohamad, Rapidah
Awang, Normah
Kamaludin, Nurul Farahana
Jotani, Mukesh M.
Tiekink, Edward R. T.
Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title_full Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title_fullStr Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title_full_unstemmed Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title_short Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) and [N-methyl-N-(2-phenyl­ethyl)­dithio­carbamato-κ(2) S,S′]tri­phenyl­tin(IV)
title_sort crystal structures and hirshfeld surface analyses of (n-hexyl-n-methyl­dithio­carbamato-κ(2) s,s′)triphenyl­tin(iv) and [n-methyl-n-(2-phenyl­ethyl)­dithio­carbamato-κ(2) s,s′]tri­phenyl­tin(iv)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947476/
https://www.ncbi.nlm.nih.gov/pubmed/29850080
http://dx.doi.org/10.1107/S2056989018005133
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