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Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile
The title organic compound, C(37)H(23)N, crystallizing in the triclinic space group P [Image: see text], has been designed, synthesized and characterized by single-crystal X-ray diffaction, MS, NMR and elemental analysis. There are alternating relatively strong and weak intermolecular π–π interactio...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947477/ https://www.ncbi.nlm.nih.gov/pubmed/29850081 http://dx.doi.org/10.1107/S2056989018005182 |
| _version_ | 1783322375182352384 |
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| author | Miao, Bao-Xi Tang, Xin-Xue Zhang, Li-Fang |
| author_facet | Miao, Bao-Xi Tang, Xin-Xue Zhang, Li-Fang |
| author_sort | Miao, Bao-Xi |
| collection | PubMed |
| description | The title organic compound, C(37)H(23)N, crystallizing in the triclinic space group P [Image: see text], has been designed, synthesized and characterized by single-crystal X-ray diffaction, MS, NMR and elemental analysis. There are alternating relatively strong and weak intermolecular π–π interactions between adjacent pyrene ring systems, forming a one-dimensional supramolecular structure. The compound is weakly fluorescent in THF solution, but it is highly emissive in the condensed phase, revealing distinct aggregation-induced emission (AIE) characteristics. |
| format | Online Article Text |
| id | pubmed-5947477 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-59474772018-05-30 Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile Miao, Bao-Xi Tang, Xin-Xue Zhang, Li-Fang Acta Crystallogr E Crystallogr Commun Research Communications The title organic compound, C(37)H(23)N, crystallizing in the triclinic space group P [Image: see text], has been designed, synthesized and characterized by single-crystal X-ray diffaction, MS, NMR and elemental analysis. There are alternating relatively strong and weak intermolecular π–π interactions between adjacent pyrene ring systems, forming a one-dimensional supramolecular structure. The compound is weakly fluorescent in THF solution, but it is highly emissive in the condensed phase, revealing distinct aggregation-induced emission (AIE) characteristics. International Union of Crystallography 2018-04-06 /pmc/articles/PMC5947477/ /pubmed/29850081 http://dx.doi.org/10.1107/S2056989018005182 Text en © Miao et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Miao, Bao-Xi Tang, Xin-Xue Zhang, Li-Fang Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title | Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title_full | Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title_fullStr | Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title_full_unstemmed | Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title_short | Synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| title_sort | synthesis, crystal structure and aggregation-induced emission of a new pyrene-based compound, 3,3-diphenyl-2-[4-(pyren-1-yl)phenyl]acrylonitrile |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947477/ https://www.ncbi.nlm.nih.gov/pubmed/29850081 http://dx.doi.org/10.1107/S2056989018005182 |
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