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6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions
The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean pla...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947488/ https://www.ncbi.nlm.nih.gov/pubmed/29850092 http://dx.doi.org/10.1107/S2056989018005959 |
Sumario: | The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean planes of the terminal methylphenol rings are 31.47 (6) and 36.03 (5)°, respectively. The sp (2)-hybridized character of the azanylylidene groups is confirmed by their bond lengths and bond angles. In the crystal, molecules are linked into centrosymmetric dimers by weak C—H⋯N interactions and connected into dimeric chains through weak C—H⋯O interactions. These chains are interconnected into a two-dimensional network parallel to (1[Image: see text]1) via weak C—H⋯π interactions. |
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