Cargando…

6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions

The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean pla...

Descripción completa

Detalles Bibliográficos
Autores principales: Arafath, Md. Azharul, Kwong, Huey Chong, Adam, Farook, Razali, Mohd. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947488/
https://www.ncbi.nlm.nih.gov/pubmed/29850092
http://dx.doi.org/10.1107/S2056989018005959
_version_ 1783322377767092224
author Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
author_facet Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
author_sort Arafath, Md. Azharul
collection PubMed
description The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean planes of the terminal methyl­phenol rings are 31.47 (6) and 36.03 (5)°, respectively. The sp (2)-hybridized character of the azanylylidene groups is confirmed by their bond lengths and bond angles. In the crystal, mol­ecules are linked into centrosymmetric dimers by weak C—H⋯N inter­actions and connected into dimeric chains through weak C—H⋯O inter­actions. These chains are inter­connected into a two-dimensional network parallel to (1[Image: see text]1) via weak C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-5947488
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-59474882018-05-30 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean planes of the terminal methyl­phenol rings are 31.47 (6) and 36.03 (5)°, respectively. The sp (2)-hybridized character of the azanylylidene groups is confirmed by their bond lengths and bond angles. In the crystal, mol­ecules are linked into centrosymmetric dimers by weak C—H⋯N inter­actions and connected into dimeric chains through weak C—H⋯O inter­actions. These chains are inter­connected into a two-dimensional network parallel to (1[Image: see text]1) via weak C—H⋯π inter­actions. International Union of Crystallography 2018-04-24 /pmc/articles/PMC5947488/ /pubmed/29850092 http://dx.doi.org/10.1107/S2056989018005959 Text en © Arafath et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
Razali, Mohd. R.
6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title_full 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title_fullStr 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title_full_unstemmed 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title_short 6,6′-[(1E,1′E)-Oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions
title_sort 6,6′-[(1e,1′e)-oxybis(4,1-phenyl­ene)bis­(aza­nylyl­idene)bis­(methanylyl­idene)]bis­(2-methyl­phenol): supra­molecular assemblies in two dimensions mediated by weak c—h⋯n, c—h⋯o and c—h⋯π inter­actions
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947488/
https://www.ncbi.nlm.nih.gov/pubmed/29850092
http://dx.doi.org/10.1107/S2056989018005959
work_keys_str_mv AT arafathmdazharul 661e1eoxybis41phenylenebisazanylylidenebismethanylylidenebis2methylphenolsupramolecularassembliesintwodimensionsmediatedbyweakchnchoandchpinteractions
AT kwonghueychong 661e1eoxybis41phenylenebisazanylylidenebismethanylylidenebis2methylphenolsupramolecularassembliesintwodimensionsmediatedbyweakchnchoandchpinteractions
AT adamfarook 661e1eoxybis41phenylenebisazanylylidenebismethanylylidenebis2methylphenolsupramolecularassembliesintwodimensionsmediatedbyweakchnchoandchpinteractions
AT razalimohdr 661e1eoxybis41phenylenebisazanylylidenebismethanylylidenebis2methylphenolsupramolecularassembliesintwodimensionsmediatedbyweakchnchoandchpinteractions