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6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions
The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean pla...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947488/ https://www.ncbi.nlm.nih.gov/pubmed/29850092 http://dx.doi.org/10.1107/S2056989018005959 |
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author | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. |
author_facet | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. |
author_sort | Arafath, Md. Azharul |
collection | PubMed |
description | The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean planes of the terminal methylphenol rings are 31.47 (6) and 36.03 (5)°, respectively. The sp (2)-hybridized character of the azanylylidene groups is confirmed by their bond lengths and bond angles. In the crystal, molecules are linked into centrosymmetric dimers by weak C—H⋯N interactions and connected into dimeric chains through weak C—H⋯O interactions. These chains are interconnected into a two-dimensional network parallel to (1[Image: see text]1) via weak C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-5947488 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-59474882018-05-30 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(28)H(24)N(2)O(3), is a flexible Schiff base, having a dihedral angle of 59.53 (5)° between the mean planes of two phenyl rings bounded in the centre by a single O atom. The dihedral angles between the mean planes of the phenyl rings bonded to the central O atom and the mean planes of the terminal methylphenol rings are 31.47 (6) and 36.03 (5)°, respectively. The sp (2)-hybridized character of the azanylylidene groups is confirmed by their bond lengths and bond angles. In the crystal, molecules are linked into centrosymmetric dimers by weak C—H⋯N interactions and connected into dimeric chains through weak C—H⋯O interactions. These chains are interconnected into a two-dimensional network parallel to (1[Image: see text]1) via weak C—H⋯π interactions. International Union of Crystallography 2018-04-24 /pmc/articles/PMC5947488/ /pubmed/29850092 http://dx.doi.org/10.1107/S2056989018005959 Text en © Arafath et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Razali, Mohd. R. 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title | 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title_full | 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title_fullStr | 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title_full_unstemmed | 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title_short | 6,6′-[(1E,1′E)-Oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak C—H⋯N, C—H⋯O and C—H⋯π interactions |
title_sort | 6,6′-[(1e,1′e)-oxybis(4,1-phenylene)bis(azanylylidene)bis(methanylylidene)]bis(2-methylphenol): supramolecular assemblies in two dimensions mediated by weak c—h⋯n, c—h⋯o and c—h⋯π interactions |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947488/ https://www.ncbi.nlm.nih.gov/pubmed/29850092 http://dx.doi.org/10.1107/S2056989018005959 |
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