Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers

The crystal structure of a platinum(II) supra­molecular building block, [Pt(dbbpy)(NCCH(3))(2)](BF(4))(2) (dbbpy = 4,4′-di-tert-butyl-2,2′-bi­pyridine, C(18)H(24)N(2)) is an example of a rare head-to-head dimer, even with the bulky tert-butyl groups of the bi­pyridine. This packing motif still enabl...

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Detalles Bibliográficos
Autores principales: Joseph, Chris, Nesterov, Vladimir N., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947490/
https://www.ncbi.nlm.nih.gov/pubmed/29850094
http://dx.doi.org/10.1107/S2056989018005923
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author Joseph, Chris
Nesterov, Vladimir N.
Smucker, Bradley W.
author_facet Joseph, Chris
Nesterov, Vladimir N.
Smucker, Bradley W.
author_sort Joseph, Chris
collection PubMed
description The crystal structure of a platinum(II) supra­molecular building block, [Pt(dbbpy)(NCCH(3))(2)](BF(4))(2) (dbbpy = 4,4′-di-tert-butyl-2,2′-bi­pyridine, C(18)H(24)N(2)) is an example of a rare head-to-head dimer, even with the bulky tert-butyl groups of the bi­pyridine. This packing motif still enables significant π–π inter­actions between two pyridyl groups, and may result from the close proximity of the tetra­fluorido­borate ions to the platinum(II) complexes, resulting in intra­molecular H⋯F distances between 2.156 and 2.573 Å.
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spelling pubmed-59474902018-05-30 Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers Joseph, Chris Nesterov, Vladimir N. Smucker, Bradley W. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of a platinum(II) supra­molecular building block, [Pt(dbbpy)(NCCH(3))(2)](BF(4))(2) (dbbpy = 4,4′-di-tert-butyl-2,2′-bi­pyridine, C(18)H(24)N(2)) is an example of a rare head-to-head dimer, even with the bulky tert-butyl groups of the bi­pyridine. This packing motif still enables significant π–π inter­actions between two pyridyl groups, and may result from the close proximity of the tetra­fluorido­borate ions to the platinum(II) complexes, resulting in intra­molecular H⋯F distances between 2.156 and 2.573 Å. International Union of Crystallography 2018-04-24 /pmc/articles/PMC5947490/ /pubmed/29850094 http://dx.doi.org/10.1107/S2056989018005923 Text en © Joseph et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Joseph, Chris
Nesterov, Vladimir N.
Smucker, Bradley W.
Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title_full Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title_fullStr Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title_full_unstemmed Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title_short Crystal structure of bis­(aceto­nitrile-κN)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)platinum(II) bis­(tetra­fluorido­borate) packing as head-to-head dimers
title_sort crystal structure of bis­(aceto­nitrile-κn)(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) n,n′)platinum(ii) bis­(tetra­fluorido­borate) packing as head-to-head dimers
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947490/
https://www.ncbi.nlm.nih.gov/pubmed/29850094
http://dx.doi.org/10.1107/S2056989018005923
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