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The preparation of an ultrastable mesoporous Cr(iii)-MOF via reductive labilization
Kinetic labilization of the Fe(iii)–O coordination bond in a mesoporous metal–organic framework, PCN-333-Fe(iii), is realized by the reduction of Fe(iii) by Cr(ii). The Fe(ii)–Cr(ii) metathesis is thus completely achieved followed by this reductive labilization process that generates PCN-333-Cr(iii)...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947515/ https://www.ncbi.nlm.nih.gov/pubmed/29861943 http://dx.doi.org/10.1039/c5sc02587g |