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Encapsulation of Crabtree's Catalyst in Sulfonated MIL‐101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment
Crabtree's catalyst was encapsulated inside the pores of the sulfonated MIL‐101(Cr) metal–organic framework (MOF) by cation exchange. This hybrid catalyst is active for the heterogeneous hydrogenation of non‐functionalized alkenes either in solution or in the gas phase. Moreover, encapsulation...
Autores principales: | Grigoropoulos, Alexios, McKay, Alasdair I., Katsoulidis, Alexandros P., Davies, Robert P., Haynes, Anthony, Brammer, Lee, Xiao, Jianliang, Weller, Andrew S., Rosseinsky, Matthew J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947555/ https://www.ncbi.nlm.nih.gov/pubmed/29377466 http://dx.doi.org/10.1002/anie.201710091 |
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