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Encapsulation of Crabtree's Catalyst in Sulfonated MIL‐101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment

Crabtree's catalyst was encapsulated inside the pores of the sulfonated MIL‐101(Cr) metal–organic framework (MOF) by cation exchange. This hybrid catalyst is active for the heterogeneous hydrogenation of non‐functionalized alkenes either in solution or in the gas phase. Moreover, encapsulation...

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Detalles Bibliográficos
Autores principales: Grigoropoulos, Alexios, McKay, Alasdair I., Katsoulidis, Alexandros P., Davies, Robert P., Haynes, Anthony, Brammer, Lee, Xiao, Jianliang, Weller, Andrew S., Rosseinsky, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947555/
https://www.ncbi.nlm.nih.gov/pubmed/29377466
http://dx.doi.org/10.1002/anie.201710091

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