Ligand‐ and Metal‐Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious

Coordination of the diazadiene diolefin ligand (trop(2)dad) to ruthenium leads to various complexes of composition [Ru(trop(2)dad)(L)]. DFT studies indicate that the closed‐shell singlet (CSS), open‐shell singlet (OSS), and triplet electronic structures of this species are close in energy, with the...

Descripción completa

Detalles Bibliográficos
Autores principales: Sinha, Vivek, Pribanic, Bruno, de Bruin, Bas, Trincado, Monica, Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947567/
https://www.ncbi.nlm.nih.gov/pubmed/29341297
http://dx.doi.org/10.1002/chem.201705957

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947567/
https://www.ncbi.nlm.nih.gov/pubmed/29341297
http://dx.doi.org/10.1002/chem.201705957

Ejemplares similares