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Ligand‐ and Metal‐Based Reactivity of a Neutral Ruthenium Diolefin Diazadiene Complex: The Innocent, the Guilty and the Suspicious
Coordination of the diazadiene diolefin ligand (trop(2)dad) to ruthenium leads to various complexes of composition [Ru(trop(2)dad)(L)]. DFT studies indicate that the closed‐shell singlet (CSS), open‐shell singlet (OSS), and triplet electronic structures of this species are close in energy, with the...
Autores principales: | Sinha, Vivek, Pribanic, Bruno, de Bruin, Bas, Trincado, Monica, Grützmacher, Hansjörg |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947567/ https://www.ncbi.nlm.nih.gov/pubmed/29341297 http://dx.doi.org/10.1002/chem.201705957 |
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