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Visible light-mediated gold-catalysed carbon(sp(2))–carbon(sp) cross-coupling

A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of alkynyltrimethylsilanes and aryl–alkynyl reductive...

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Detalles Bibliográficos
Autores principales: Kim, Suhong, Rojas-Martin, Jaime, Toste, F. Dean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947751/
https://www.ncbi.nlm.nih.gov/pubmed/29861967
http://dx.doi.org/10.1039/c5sc03025k