Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium

In the title compound, [OsBr(C(10)H(14))(C(7)H(5)O(2))], the central Os(II) ion is ligated by a hexa­haptic η(6) p-cymene ring, a Br(−) ligand and two O atoms of a chelating tropolonate group. The p-cymene ligand presents more than one conformation, giving rise to a discrete disorder, which was mode...

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Detalles Bibliográficos
Autores principales: Clayton, Hadley S., Tapala, Kgaugelo C., Lemmerer, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947785/
https://www.ncbi.nlm.nih.gov/pubmed/29765705
http://dx.doi.org/10.1107/S2056989018001391
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author Clayton, Hadley S.
Tapala, Kgaugelo C.
Lemmerer, Andreas
author_facet Clayton, Hadley S.
Tapala, Kgaugelo C.
Lemmerer, Andreas
author_sort Clayton, Hadley S.
collection PubMed
description In the title compound, [OsBr(C(10)H(14))(C(7)H(5)O(2))], the central Os(II) ion is ligated by a hexa­haptic η(6) p-cymene ring, a Br(−) ligand and two O atoms of a chelating tropolonate group. The p-cymene ligand presents more than one conformation, giving rise to a discrete disorder, which was modelled with two different orientations with occupancy values of 0.561 (15) and 0.439 (15). The crystal packing features C—H⋯O and C—H⋯Br hydrogen bonding. Aromatic π–π stacking inter­actions are also observed between adjacent non-benzenoid aromatic tropolone rings.
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spelling pubmed-59477852018-05-15 Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium Clayton, Hadley S. Tapala, Kgaugelo C. Lemmerer, Andreas Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [OsBr(C(10)H(14))(C(7)H(5)O(2))], the central Os(II) ion is ligated by a hexa­haptic η(6) p-cymene ring, a Br(−) ligand and two O atoms of a chelating tropolonate group. The p-cymene ligand presents more than one conformation, giving rise to a discrete disorder, which was modelled with two different orientations with occupancy values of 0.561 (15) and 0.439 (15). The crystal packing features C—H⋯O and C—H⋯Br hydrogen bonding. Aromatic π–π stacking inter­actions are also observed between adjacent non-benzenoid aromatic tropolone rings. International Union of Crystallography 2018-02-02 /pmc/articles/PMC5947785/ /pubmed/29765705 http://dx.doi.org/10.1107/S2056989018001391 Text en © Clayton et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Clayton, Hadley S.
Tapala, Kgaugelo C.
Lemmerer, Andreas
Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title_full Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title_fullStr Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title_full_unstemmed Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title_short Crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) O,O′)osmium
title_sort crystal structure of bromido(η(6)-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ(2) o,o′)osmium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947785/
https://www.ncbi.nlm.nih.gov/pubmed/29765705
http://dx.doi.org/10.1107/S2056989018001391
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