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Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ(2) S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ(2) S,S′]triphenyltin(IV)
The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C(4)H(9))(2)(C(7)H(14)NO(2)S(2))(2)], (I), and [Sn(C(6)H(5))(3)(C(5)H(10)NOS(2))], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoid...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947791/ https://www.ncbi.nlm.nih.gov/pubmed/29765711 http://dx.doi.org/10.1107/S2056989018001901 |
Sumario: | The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C(4)H(9))(2)(C(7)H(14)NO(2)S(2))(2)], (I), and [Sn(C(6)H(5))(3)(C(5)H(10)NOS(2))], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetrahedral geometry in (II). The complete molecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), molecules self-assemble into a supramolecular array parallel to (10-1) via methylene-C—H⋯O(methoxy) interactions. In the crystal of (II), supramolecular dimers are formed via pairs of weak phenyl-C—H⋯π(phenyl) contacts. In each of (I) and (II), the specified assemblies connect into a three-dimensional architecture without directional interactions between them. Hirshfeld surface analyses confirm the importance of H⋯H contacts in the molecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short methoxy-H⋯H(butyl) contacts between layers. |
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