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Crystal structure of dimethyl 1-oxo-2,4-diphenyl-1,2-dihydronaphthalene-2,3-dicarboxylate
In the title compound, C(26)H(20)O(5), a 1,2-dihydronaphthalene derivative, the cyclohexa-1,3-diene ring of the 1,2-dihydronaphthalene ring system adopts a half-chair conformation. The mean plane of the 1,2-dihydronapthalene ring system makes dihedral angles of 86.23 (6) and 64.80 (7)° with t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947801/ https://www.ncbi.nlm.nih.gov/pubmed/29765721 http://dx.doi.org/10.1107/S2056989018002360 |
Sumario: | In the title compound, C(26)H(20)O(5), a 1,2-dihydronaphthalene derivative, the cyclohexa-1,3-diene ring of the 1,2-dihydronaphthalene ring system adopts a half-chair conformation. The mean plane of the 1,2-dihydronapthalene ring system makes dihedral angles of 86.23 (6) and 64.80 (7)° with two phenyl rings. The carbonyl O atom attached to the dihydronaphthalene ring system deviates from the mean plane of the 1,2-dihydronaphthalene ring system by 0.618 (1) Å. In the crystal, the molecules are linked into layers parallel to the bc plane via two kinds of C—H⋯O interactions, one of which forms a C(10) chain motif running along the c-axis direction and the other forms an R (2) (2)(6) ring motif. Adjacent layers are further connected by C—H⋯π and offset π–π interactions [centroid–centroid distance = 3.6318 (9) Å]. |
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