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Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds
The molecule of the title compound, C(13)H(10)ClNO, (I), which contains an intramolecular O—H⋯N hydrogen bond, is almost planar: the dihedral angle between the two aryl rings is only 3.31 (9)°. The molecules of (I) are linked into sheets by two C—H⋯π(arene) hydrogen bonds and the sheets are linke...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947807/ https://www.ncbi.nlm.nih.gov/pubmed/29765727 http://dx.doi.org/10.1107/S205698901800244X |
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author | Girisha, Marisiddaiah Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher |
author_facet | Girisha, Marisiddaiah Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher |
author_sort | Girisha, Marisiddaiah |
collection | PubMed |
description | The molecule of the title compound, C(13)H(10)ClNO, (I), which contains an intramolecular O—H⋯N hydrogen bond, is almost planar: the dihedral angle between the two aryl rings is only 3.31 (9)°. The molecules of (I) are linked into sheets by two C—H⋯π(arene) hydrogen bonds and the sheets are linked into a three-dimensional structure by O—H⋯O hydrogen bonds. Comparisons are made with the structures of a number of related compounds. |
format | Online Article Text |
id | pubmed-5947807 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-59478072018-05-15 Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds Girisha, Marisiddaiah Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Research Communications The molecule of the title compound, C(13)H(10)ClNO, (I), which contains an intramolecular O—H⋯N hydrogen bond, is almost planar: the dihedral angle between the two aryl rings is only 3.31 (9)°. The molecules of (I) are linked into sheets by two C—H⋯π(arene) hydrogen bonds and the sheets are linked into a three-dimensional structure by O—H⋯O hydrogen bonds. Comparisons are made with the structures of a number of related compounds. International Union of Crystallography 2018-02-23 /pmc/articles/PMC5947807/ /pubmed/29765727 http://dx.doi.org/10.1107/S205698901800244X Text en © Girisha et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Girisha, Marisiddaiah Yathirajan, Hemmige S. Rathore, Ravindranath S. Glidewell, Christopher Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title | Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title_full | Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title_fullStr | Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title_full_unstemmed | Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title_short | Reinvestigation of the crystal structure of N-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing O—H⋯N, O—H⋯O and C—H⋯π(arene) hydrogen bonds |
title_sort | reinvestigation of the crystal structure of n-(4-chlorobenzylidene)-2-hydroxyaniline: a three-dimensional structure containing o—h⋯n, o—h⋯o and c—h⋯π(arene) hydrogen bonds |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5947807/ https://www.ncbi.nlm.nih.gov/pubmed/29765727 http://dx.doi.org/10.1107/S205698901800244X |
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