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Carbide complexes as π-acceptor ligands

The π-accepting character of a terminal carbide complex acting as a ligand is demonstrated experimentally and corroborates earlier theoretical predictions. As a result, coordination of a terminal ruthenium carbide complex to electron-rich metal centres is shown to provide a facile and versatile rout...

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Detalles Bibliográficos
Autores principales: Reinholdt, Anders, Vibenholt, Johan E., Morsing, Thorbjørn J., Schau-Magnussen, Magnus, Reeler, Nini E. A., Bendix, Jesper
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950194/
https://www.ncbi.nlm.nih.gov/pubmed/29861908
http://dx.doi.org/10.1039/c5sc02077h