A five-coordinate Mn(iv) intermediate in biological water oxidation: spectroscopic signature and a pivot mechanism for water binding

Among the four photo-driven transitions of the water-oxidizing tetramanganese–calcium cofactor of biological photosynthesis, the second-last step of the catalytic cycle, that is the S(2) to S(3) state transition, is the crucial step that poises the catalyst for the final O–O bond formation. This tra...

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Detalles Bibliográficos
Autores principales: Retegan, Marius, Krewald, Vera, Mamedov, Fikret, Neese, Frank, Lubitz, Wolfgang, Cox, Nicholas, Pantazis, Dimitrios A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950799/
https://www.ncbi.nlm.nih.gov/pubmed/29861966
http://dx.doi.org/10.1039/c5sc03124a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950799/
https://www.ncbi.nlm.nih.gov/pubmed/29861966
http://dx.doi.org/10.1039/c5sc03124a

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