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A five-coordinate Mn(iv) intermediate in biological water oxidation: spectroscopic signature and a pivot mechanism for water binding
Among the four photo-driven transitions of the water-oxidizing tetramanganese–calcium cofactor of biological photosynthesis, the second-last step of the catalytic cycle, that is the S(2) to S(3) state transition, is the crucial step that poises the catalyst for the final O–O bond formation. This tra...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950799/ https://www.ncbi.nlm.nih.gov/pubmed/29861966 http://dx.doi.org/10.1039/c5sc03124a |