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Water oxidation catalysed by iron complex of N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron–oxo intermediates and density functional theory calculations
The macrocyclic [Fe(III)(L1)Cl(2)](+) (1, L1 = N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane) complex is an active catalyst for the oxidation of water to oxygen using [NH(4)](2)[Ce(IV)(NO(3))(6)] (CAN), NaIO(4), or Oxone as the oxidant. The mechanism of 1-catalysed water oxidation was examined by...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5950833/ https://www.ncbi.nlm.nih.gov/pubmed/29861914 http://dx.doi.org/10.1039/c5sc01680k |