Cargando…

Identification of diborane(4) with bridging B–H–B bonds

The irradiation of diborane(6) dispersed in solid neon at 3 K with tunable far-ultraviolet light from a synchrotron yielded a set of IR absorption lines, the pattern of which implies a carrier containing two boron atoms. According to isotope effects and quantum-chemical calculations, we identified t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Chou, Sheng-Lung, Lo, Jen-Iu, Peng, Yu-Chain, Lin, Meng-Yeh, Lu, Hsiao-Chi, Cheng, Bing-Ming, Ogilvie, J. F.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951111/ https://www.ncbi.nlm.nih.gov/pubmed/29861928 http://dx.doi.org/10.1039/c5sc02586a

Ejemplares similares

Identification of cyc-B(3)H(3) with Three Bridging B–H–B Bonds in a Six-Membered Ring
por: Chou, Sheng-Lung, et al.
Publicado: (2017)

Chiral diboranes as catalysts for the stereoselective organopolymerization of epoxides
por: Sirin-Sariaslan, Ayla, et al.
Publicado: (2022)

Electronic and Vibrational Absorption Spectra of NH(2) in Solid Ne
por: Chou, Sheng-Lung, et al.
Publicado: (2019)

Thermal reaction and luminescence of long-lived N (2)D in N(2) ice
por: Lo, Jen-Iu, et al.
Publicado: (2019)

Magnesium Boryl Reactivity with 9‐BBN and Ph(3)B: Rational B−B′ Bond Formation and Diborane Isomerization
por: Pécharman, Anne‐Frédérique, et al.
Publicado: (2017)

B–B vs. B–H Bond Activation in a (μ‐Hydrido)diborane(4) Anion upon Cycloaddition with CO(2), Isocyanates, or Carbodiimides
por: Trageser, Timo, et al.
Publicado: (2021)

Large-bite diboranes for the μ(1,2) complexation of hydrazine and cyanide
por: Chen, Chang-Hong, et al.
Publicado: (2018)

A redox-active diborane platform performs C(sp(3))–H activation and nucleophilic substitution reactions
por: Kaese, Thomas, et al.
Publicado: (2018)

Bistriazoles Connected Through a B−B Bridge, Synthesized by Highly Selective Dipolar Cycloaddition Reactions of a Diazido‐diborane(4)
por: Vogler, Daniel, et al.
Publicado: (2022)

Snapshots of magnesium-centred diborane heterolysis by an outer sphere S(N)2 process
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2019)

A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals
por: Mao, Xiaofeng, et al.
Publicado: (2022)

Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes
por: Brunecker, Carina, et al.
Publicado: (2020)

Exploring unsymmetrical diboranes(4) as boryl ligand precursors: platinum(ii) bis-boryl complexes
por: Drescher (née Oschmann), Wiebke, et al.
Publicado: (2019)

Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent
por: Asakawa, Hiroki, et al.
Publicado: (2014)

A Chemiluminescent Tetraaryl Diborane(4) Tetraanion
por: Budy, Hendrik, et al.
Publicado: (2021)

Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene–pyridine complex and ortho-functionalized pyridine derivatives
por: Katsuma, Yuhei, et al.
Publicado: (2017)

Polymorphic transitions of diborane at sub- and near-megabar pressures
por: Torabi, Amin, et al.
Publicado: (2015)

Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile
por: Schön, Florian, et al.
Publicado: (2020)

Reactivity of hydride bridges in a high-spin [Fe(3)(μ-H)(3)](3+) cluster: reversible H(2)/CO exchange and Fe–H/B–F bond metathesis
por: Anderton, Kevin J., et al.
Publicado: (2017)

Molecular Mechanics Study of the Cyclic and Unsymmetric Diborane(4) Compounds
por: Rendtorff, N., et al.
Publicado: (2003)

Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes
por: Thiess, Torsten, et al.
Publicado: (2020)

Single and double activation of acetone by isolobal B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds
por: Böhnke, Julian, et al.
Publicado: (2018)

Heterolytic bond activation at gold: evidence for gold(iii) H–B, H–Si complexes, H–H and H–C cleavage
por: Rocchigiani, Luca, et al.
Publicado: (2019)

The boron–boron triple bond in NHC→B[triple bond, length as m-dash]B←NHC
por: Holzmann, Nicole, et al.
Publicado: (2015)

Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
por: Pécharman, Anne-Frédérique, et al.
Publicado: (2017)

Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
por: Brückner, Tobias, et al.
Publicado: (2019)

Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation
por: Yang, Kai, et al.
Publicado: (2018)

Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis
por: Prey, Sven E., et al.
Publicado: (2022)

Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different
por: Ríos, Pablo, et al.
Publicado: (2022)

Heterometallic bond activation enabled by unsymmetrical ligand scaffolds: bridging the opposites
por: Govindarajan, R., et al.
Publicado: (2022)

On donor–acceptor-bridging intramolecular hydrogen bonds in NIR-TADF molecules
por: Weber, Fabian, et al.
Publicado: (2023)

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)

The smallest 4f-metalla-aromatic molecule of cyclo-PrB(2)(−) with Pr–B multiple bonds
por: Wang, Zhen-Ling, et al.
Publicado: (2022)

Bond dissociation energies of X–H bonds in proteins
por: Treyde, Wojtek, et al.
Publicado: (2022)

Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes
por: Cui, Jingjing, et al.
Publicado: (2021)

Site-selective functionalization of remote aliphatic C–H bonds via C–H metallation
por: Zhang, Qi, et al.
Publicado: (2020)

Mechanism of the cooperative Si–H bond activation at Ru–S bonds
por: Stahl, Timo, et al.
Publicado: (2015)

Pushing the limits of the hydrogen bond enhanced halogen bond—the case of the C–H hydrogen bond
por: Decato, Daniel A., et al.
Publicado: (2022)

[(Cp(2)M)(2)B(9)H(11)] (M = Zr or Hf): early transition metal ‘guarded’ heptaborane with strong covalent and electrostatic bonding
por: De, Anangsha, et al.
Publicado: (2018)

Cooperative B–H bond activation: dual site borane activation by redox active κ(2)-N,S-chelated complexes
por: Zafar, Mohammad, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_hba2glj2j6hopqmr4u30tu5k0g