Metal-only Lewis pairs between group 10 metals and Tl(i) or Ag(i): insights into the electronic consequences of Z-type ligand binding

Complexes bearing electron rich transition metal centers, especially those displaying coordinative unsaturation, are well-suited to form reverse-dative σ-interactions with Lewis acids. Herein we demonstrate the generality of zerovalent, group 10 m-terphenyl isocyanide complexes to form reverse-dativ...

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Detalles Bibliográficos
Autores principales: Barnett, Brandon R., Moore, Curtis E., Chandrasekaran, Perumalreddy, Sproules, Stephen, Rheingold, Arnold L., DeBeer, Serena, Figueroa, Joshua S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951196/
https://www.ncbi.nlm.nih.gov/pubmed/29861954
http://dx.doi.org/10.1039/c5sc03104d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951196/
https://www.ncbi.nlm.nih.gov/pubmed/29861954
http://dx.doi.org/10.1039/c5sc03104d

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