Enhancement of CO(2) Uptake and Selectivity in a Metal–Organic Framework by the Incorporation of Thiophene Functionality

[Image: see text] The complex [Zn(2)(tdc)(2)dabco] (H(2)tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in carbon dioxide (CO(2)) uptake and CO(2)/dinitrogen (N(2)) selectivity compared to the nonthiophene analogue [Zn(2)(bdc)(2)dabco] (H(2)bdc = be...

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Detalles Bibliográficos
Autores principales: Bolotov, Vsevolod A., Kovalenko, Konstantin A., Samsonenko, Denis G., Han, Xue, Zhang, Xinran, Smith, Gemma L., McCormick, Laura J., Teat, Simon J., Yang, Sihai, Lennox, Matthew J., Henley, Alice, Besley, Elena, Fedin, Vladimir P., Dybtsev, Danil N., Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951605/
https://www.ncbi.nlm.nih.gov/pubmed/29683657
http://dx.doi.org/10.1021/acs.inorgchem.8b00138

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