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Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals
[Image: see text] Au(I) in combination with AgOTf enables the unprecedented direct and α-stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of the enol ether glycoside. The room...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5951607/ https://www.ncbi.nlm.nih.gov/pubmed/28934850 http://dx.doi.org/10.1021/jacs.7b08898 |