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Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation

Pressure-driven, superfast organic solvent filtration membranes have significant practical applications. An excellent filtration membrane should exhibit high selectivity and permeation in aqueous and organic solvents to meet increasing industrial demand. Here, we report an amino functionalized boron...

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Autores principales: Chen, Cheng, Wang, Jiemin, Liu, Dan, Yang, Chen, Liu, Yuchen, Ruoff, Rodney S., Lei, Weiwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954095/
https://www.ncbi.nlm.nih.gov/pubmed/29765025
http://dx.doi.org/10.1038/s41467-018-04294-6
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author Chen, Cheng
Wang, Jiemin
Liu, Dan
Yang, Chen
Liu, Yuchen
Ruoff, Rodney S.
Lei, Weiwei
author_facet Chen, Cheng
Wang, Jiemin
Liu, Dan
Yang, Chen
Liu, Yuchen
Ruoff, Rodney S.
Lei, Weiwei
author_sort Chen, Cheng
collection PubMed
description Pressure-driven, superfast organic solvent filtration membranes have significant practical applications. An excellent filtration membrane should exhibit high selectivity and permeation in aqueous and organic solvents to meet increasing industrial demand. Here, we report an amino functionalized boron nitride (FBN) based filtration membrane with a nanochannel network for molecular separation and permeation. This membrane is highly stable in water and in several organic solvents and shows high transport performance for solvents depending on the membranes’ thickness. In addition, the FBN membrane is applicable for solute screening in water as well as in organic solvents. More importantly, the FBN membranes are very stable in acidic, alkaline and oxidative media for up to one month. The fast-flow rate and good separation performance of the FBN membranes can be attributed to their stable networks of nanochannels and thin laminar structure, which provide the membranes with beneficial properties for practical separation and purification processes.
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spelling pubmed-59540952018-05-17 Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation Chen, Cheng Wang, Jiemin Liu, Dan Yang, Chen Liu, Yuchen Ruoff, Rodney S. Lei, Weiwei Nat Commun Article Pressure-driven, superfast organic solvent filtration membranes have significant practical applications. An excellent filtration membrane should exhibit high selectivity and permeation in aqueous and organic solvents to meet increasing industrial demand. Here, we report an amino functionalized boron nitride (FBN) based filtration membrane with a nanochannel network for molecular separation and permeation. This membrane is highly stable in water and in several organic solvents and shows high transport performance for solvents depending on the membranes’ thickness. In addition, the FBN membrane is applicable for solute screening in water as well as in organic solvents. More importantly, the FBN membranes are very stable in acidic, alkaline and oxidative media for up to one month. The fast-flow rate and good separation performance of the FBN membranes can be attributed to their stable networks of nanochannels and thin laminar structure, which provide the membranes with beneficial properties for practical separation and purification processes. Nature Publishing Group UK 2018-05-15 /pmc/articles/PMC5954095/ /pubmed/29765025 http://dx.doi.org/10.1038/s41467-018-04294-6 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Chen, Cheng
Wang, Jiemin
Liu, Dan
Yang, Chen
Liu, Yuchen
Ruoff, Rodney S.
Lei, Weiwei
Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title_full Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title_fullStr Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title_full_unstemmed Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title_short Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
title_sort functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954095/
https://www.ncbi.nlm.nih.gov/pubmed/29765025
http://dx.doi.org/10.1038/s41467-018-04294-6
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