A versatile synthetic route for the preparation of titanium metal–organic frameworks

Exploitation of new titanium metal–organic frameworks (Ti-MOFs) with high crystallinity has been attracting great attention due to their vast application potential in photocatalysis. Herein a versatile synthetic strategy, namely, High Valence Metathesis and Oxidation (HVMO), is developed to synthesi...

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Detalles Bibliográficos
Autores principales: Zou, Lanfang, Feng, Dawei, Liu, Tian-Fu, Chen, Ying-Pin, Yuan, Shuai, Wang, Kecheng, Wang, Xuan, Fordham, Stephen, Zhou, Hong-Cai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5954845/
https://www.ncbi.nlm.nih.gov/pubmed/29896371
http://dx.doi.org/10.1039/c5sc03620h
Descripción
Sumario:Exploitation of new titanium metal–organic frameworks (Ti-MOFs) with high crystallinity has been attracting great attention due to their vast application potential in photocatalysis. Herein a versatile synthetic strategy, namely, High Valence Metathesis and Oxidation (HVMO), is developed to synthesize a series of Ti-MOFs with predesigned topologies and structures. The crystallinity of these Ti-MOFs was well maintained throughout, as confirmed by powder X-ray diffraction and gas adsorption measurements. Significantly, there were only a few examples of Ti-MOFs, not to mention a general synthetic strategy for various kinds of Ti-MOFs in the literature. This contribution also illustrates the intriguing potential of Ti-MOF platforms in photocatalysis.

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