Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)

In the title compound, [Lu(C(7)H(7))(3)(C(4)H(8)O)(2)] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η(1)-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through...

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Detalles Bibliográficos
Autores principales: Saliu, Kuburat O., Takats, Josef, McDonald, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956313/
https://www.ncbi.nlm.nih.gov/pubmed/29850030
http://dx.doi.org/10.1107/S2056989017018254
Descripción
Sumario:In the title compound, [Lu(C(7)H(7))(3)(C(4)H(8)O)(2)] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η(1)-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl­ene C atom, resulting in a modified trigonal–bipyramidal coordination geometry about the Lu center.

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