Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)

In the title compound, [Lu(C(7)H(7))(3)(C(4)H(8)O)(2)] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η(1)-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through...

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Detalles Bibliográficos
Autores principales: Saliu, Kuburat O., Takats, Josef, McDonald, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956313/
https://www.ncbi.nlm.nih.gov/pubmed/29850030
http://dx.doi.org/10.1107/S2056989017018254
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author Saliu, Kuburat O.
Takats, Josef
McDonald, Robert
author_facet Saliu, Kuburat O.
Takats, Josef
McDonald, Robert
author_sort Saliu, Kuburat O.
collection PubMed
description In the title compound, [Lu(C(7)H(7))(3)(C(4)H(8)O)(2)] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η(1)-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl­ene C atom, resulting in a modified trigonal–bipyramidal coordination geometry about the Lu center.
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spelling pubmed-59563132018-05-30 Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III) Saliu, Kuburat O. Takats, Josef McDonald, Robert Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Lu(C(7)H(7))(3)(C(4)H(8)O)(2)] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η(1)-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl­ene C atom, resulting in a modified trigonal–bipyramidal coordination geometry about the Lu center. International Union of Crystallography 2018-01-09 /pmc/articles/PMC5956313/ /pubmed/29850030 http://dx.doi.org/10.1107/S2056989017018254 Text en © Saliu et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Saliu, Kuburat O.
Takats, Josef
McDonald, Robert
Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title_full Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title_fullStr Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title_full_unstemmed Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title_short Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)
title_sort crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κo)lutetium(iii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956313/
https://www.ncbi.nlm.nih.gov/pubmed/29850030
http://dx.doi.org/10.1107/S2056989017018254
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AT takatsjosef crystalstructureoftribenzylbistetrahydrofurankolutetiumiii
AT mcdonaldrobert crystalstructureoftribenzylbistetrahydrofurankolutetiumiii

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