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Crystal structure of the acyclic form of 1-deoxy-1-[(4-methoxyphenyl)(methyl)amino]-d-fructose
The title compound, C(14)H(21)NO(6), (I), crystallizes exclusively in the acyclic keto form. In solution of (I), the acyclic tautomer represents only 10% of the population in equilibrium, with the other 90% consisting of β-pyranose, β-furanose, α-pyranose, and α-furanose cyclic forms. The carboh...
Autores principales: | Mossine, Valeri V., Barnes, Charles L., Mawhinney, Thomas P. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956321/ https://www.ncbi.nlm.nih.gov/pubmed/29850038 http://dx.doi.org/10.1107/S2056989018000099 |
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