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The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-dimethylhydrazin-1-ylidene)methyl]-1′-(diphenylphosphorothioyl)ferrocene
The asymmetric unit of the title compound, [Fe(C(8)H(11)N(2))(C(17)H(14)PS)], contains two independent molecules (A and B) with very similar conformations. Each molecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur diphenylphosphine and by a dime...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956322/ https://www.ncbi.nlm.nih.gov/pubmed/29850039 http://dx.doi.org/10.1107/S2056989018000440 |
Sumario: | The asymmetric unit of the title compound, [Fe(C(8)H(11)N(2))(C(17)H(14)PS)], contains two independent molecules (A and B) with very similar conformations. Each molecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur diphenylphosphine and by a dimethylhydrazine, –C(H)=N—N(CH(3))(2), fragment. The two independent molecules are linked by a C—H⋯N hydrogen bond. In the crystal, the A–B dimer is linked by a pair of C—H⋯S hydrogen bonds, forming a centrosymmetric four-molecule arrangement. These units are linked by C—H⋯π interactions, forming a supramolecular three-dimensional structure. |
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