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The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene

The asymmetric unit of the title compound, [Fe(C(8)H(11)N(2))(C(17)H(14)PS)], contains two independent mol­ecules (A and B) with very similar conformations. Each mol­ecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur di­phenyl­phosphine and by a di­me...

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Autores principales: Mouas, Toma Nardjes, Daran, Jean-Claude, Merazig, Hocine, Manoury, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956322/
https://www.ncbi.nlm.nih.gov/pubmed/29850039
http://dx.doi.org/10.1107/S2056989018000440
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author Mouas, Toma Nardjes
Daran, Jean-Claude
Merazig, Hocine
Manoury, Eric
author_facet Mouas, Toma Nardjes
Daran, Jean-Claude
Merazig, Hocine
Manoury, Eric
author_sort Mouas, Toma Nardjes
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(8)H(11)N(2))(C(17)H(14)PS)], contains two independent mol­ecules (A and B) with very similar conformations. Each mol­ecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur di­phenyl­phosphine and by a di­methyl­hydrazine, –C(H)=N—N(CH(3))(2), fragment. The two independent mol­ecules are linked by a C—H⋯N hydrogen bond. In the crystal, the A–B dimer is linked by a pair of C—H⋯S hydrogen bonds, forming a centrosymmetric four-mol­ecule arrangement. These units are linked by C—H⋯π inter­actions, forming a supra­molecular three-dimensional structure.
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spelling pubmed-59563222018-05-30 The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene Mouas, Toma Nardjes Daran, Jean-Claude Merazig, Hocine Manoury, Eric Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Fe(C(8)H(11)N(2))(C(17)H(14)PS)], contains two independent mol­ecules (A and B) with very similar conformations. Each mol­ecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur di­phenyl­phosphine and by a di­methyl­hydrazine, –C(H)=N—N(CH(3))(2), fragment. The two independent mol­ecules are linked by a C—H⋯N hydrogen bond. In the crystal, the A–B dimer is linked by a pair of C—H⋯S hydrogen bonds, forming a centrosymmetric four-mol­ecule arrangement. These units are linked by C—H⋯π inter­actions, forming a supra­molecular three-dimensional structure. International Union of Crystallography 2018-01-12 /pmc/articles/PMC5956322/ /pubmed/29850039 http://dx.doi.org/10.1107/S2056989018000440 Text en © Mouas et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Mouas, Toma Nardjes
Daran, Jean-Claude
Merazig, Hocine
Manoury, Eric
The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title_full The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title_fullStr The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title_full_unstemmed The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title_short The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
title_sort crystal structure of a new ferrocenyl p,n ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956322/
https://www.ncbi.nlm.nih.gov/pubmed/29850039
http://dx.doi.org/10.1107/S2056989018000440
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