Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one

In the title compound, 3-[(2-acetamido­phen­yl)imino]­butan-2-one, C(12)H(14)N(2)O(2), the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03 (14)°. The acetamido unit is essentially cop...

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Detalles Bibliográficos
Autores principales: Zhai, Feng, Solomon, Joseph B., Filatov, Alexander S., Jordan, Richard F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956335/
https://www.ncbi.nlm.nih.gov/pubmed/29850052
http://dx.doi.org/10.1107/S2056989018000749
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author Zhai, Feng
Solomon, Joseph B.
Filatov, Alexander S.
Jordan, Richard F.
author_facet Zhai, Feng
Solomon, Joseph B.
Filatov, Alexander S.
Jordan, Richard F.
author_sort Zhai, Feng
collection PubMed
description In the title compound, 3-[(2-acetamido­phen­yl)imino]­butan-2-one, C(12)H(14)N(2)O(2), the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03 (14)°. The acetamido unit is essentially coplanar with the benzene ring. In the crystal, mol­ecules are connected into chains along the c axis through C—H⋯O hydrogen bonds, with two adjacent chains being hinged by C—H⋯O hydrogen bonds.
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spelling pubmed-59563352018-05-30 Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one Zhai, Feng Solomon, Joseph B. Filatov, Alexander S. Jordan, Richard F. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, 3-[(2-acetamido­phen­yl)imino]­butan-2-one, C(12)H(14)N(2)O(2), the imine C=N bond is essentially coplanar with the ketone C=O bond in an s-trans conformation. The benzene ring is twisted away from the plane of the C=N bond by 53.03 (14)°. The acetamido unit is essentially coplanar with the benzene ring. In the crystal, mol­ecules are connected into chains along the c axis through C—H⋯O hydrogen bonds, with two adjacent chains being hinged by C—H⋯O hydrogen bonds. International Union of Crystallography 2018-01-19 /pmc/articles/PMC5956335/ /pubmed/29850052 http://dx.doi.org/10.1107/S2056989018000749 Text en © Zhai et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Zhai, Feng
Solomon, Joseph B.
Filatov, Alexander S.
Jordan, Richard F.
Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title_full Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title_fullStr Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title_full_unstemmed Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title_short Crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
title_sort crystal structure of 3-[(2-acetamido­phen­yl)imino]­butan-2-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956335/
https://www.ncbi.nlm.nih.gov/pubmed/29850052
http://dx.doi.org/10.1107/S2056989018000749
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