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[4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium
The title compound, {Al[O-2,6-(Ph(2)CH)(2)-4-(t)BuC(6)H(2)]Et(2)(THF)} or [Al(C(2)H(5))(2)(C(36)H(33)O)(C(4)H(8)O)], was formed in the reaction between 4-tert-butyl-2,6-bis(diphenylmethyl)phenol and triethylaluminum in the presence of THF (THF is tetrahydrofuran) and recrystallized from hexa...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956341/ https://www.ncbi.nlm.nih.gov/pubmed/29850058 http://dx.doi.org/10.1107/S2056989018001172 |
| _version_ | 1783323870059560960 |
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| author | Minyaev, Mikhail E. Nifant’ev, Ilya E. Churakov, Andrei V. Shlyahtin, Andrei V. |
| author_facet | Minyaev, Mikhail E. Nifant’ev, Ilya E. Churakov, Andrei V. Shlyahtin, Andrei V. |
| author_sort | Minyaev, Mikhail E. |
| collection | PubMed |
| description | The title compound, {Al[O-2,6-(Ph(2)CH)(2)-4-(t)BuC(6)H(2)]Et(2)(THF)} or [Al(C(2)H(5))(2)(C(36)H(33)O)(C(4)H(8)O)], was formed in the reaction between 4-tert-butyl-2,6-bis(diphenylmethyl)phenol and triethylaluminum in the presence of THF (THF is tetrahydrofuran) and recrystallized from hexane. The structure has monoclinic (P2(1)/n) symmetry with a single Al atom in the asymmetric unit. The terminal C atom of one ethyl substituent is nearly equally disordered over two positions. The complex possesses catalytic activity in the ring-opening polymerization of ∊-caprolactone. |
| format | Online Article Text |
| id | pubmed-5956341 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-59563412018-05-30 [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium Minyaev, Mikhail E. Nifant’ev, Ilya E. Churakov, Andrei V. Shlyahtin, Andrei V. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {Al[O-2,6-(Ph(2)CH)(2)-4-(t)BuC(6)H(2)]Et(2)(THF)} or [Al(C(2)H(5))(2)(C(36)H(33)O)(C(4)H(8)O)], was formed in the reaction between 4-tert-butyl-2,6-bis(diphenylmethyl)phenol and triethylaluminum in the presence of THF (THF is tetrahydrofuran) and recrystallized from hexane. The structure has monoclinic (P2(1)/n) symmetry with a single Al atom in the asymmetric unit. The terminal C atom of one ethyl substituent is nearly equally disordered over two positions. The complex possesses catalytic activity in the ring-opening polymerization of ∊-caprolactone. International Union of Crystallography 2018-01-26 /pmc/articles/PMC5956341/ /pubmed/29850058 http://dx.doi.org/10.1107/S2056989018001172 Text en © Minyaev et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Minyaev, Mikhail E. Nifant’ev, Ilya E. Churakov, Andrei V. Shlyahtin, Andrei V. [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title | [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title_full | [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title_fullStr | [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title_full_unstemmed | [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title_short | [4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium |
| title_sort | [4-tert-butyl-2,6-bis(diphenylmethyl)phenolato-κo]diethyl(tetrahydrofuran-κo)aluminium |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956341/ https://www.ncbi.nlm.nih.gov/pubmed/29850058 http://dx.doi.org/10.1107/S2056989018001172 |
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