Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ(3)-tmps)(CO)(2)Nb[triple bond, length as m-dash]E–R] (E = Si, Ge, Sn; tmps = MeSi(CH(2)PMe(2))(3); R = aryl)

A systematic, efficient approach to first complexes containing a triple bond between niobium and the elements silicon, germanium or tin is reported. The approach involves a metathetical exchange of the niobium-centered nucleophile (NMe(4))[Nb(CO)(4)(κ(2)-tmps)] (1) (tmps = MeSi(CH(2)PMe(2))(3)) with...

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Detalles Bibliográficos
Autores principales: Filippou, Alexander C., Hoffmann, David, Schnakenburg, Gregor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956830/
https://www.ncbi.nlm.nih.gov/pubmed/29896377
http://dx.doi.org/10.1039/c7sc02708g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5956830/
https://www.ncbi.nlm.nih.gov/pubmed/29896377
http://dx.doi.org/10.1039/c7sc02708g

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