Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones via dynamic kinetic resolution

A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolution, simultaneously creating two contiguous s...

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Detalles Bibliográficos
Autores principales: Zatolochnaya, Olga V., Rodríguez, Sonia, Zhang, Yongda, Lao, Kendricks S., Tcyrulnikov, Sergei, Li, Guisheng, Wang, Xiao-Jun, Qu, Bo, Biswas, Soumik, Mangunuru, Hari P. R., Rivalti, Daniel, Sieber, Joshua D., Desrosiers, Jean-Nicolas, Leung, Joyce C., Grinberg, Nelu, Lee, Heewon, Haddad, Nizar, Yee, Nathan K., Song, Jinhua J., Kozlowski, Marisa C., Senanayake, Chris H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5958347/
https://www.ncbi.nlm.nih.gov/pubmed/29896393
http://dx.doi.org/10.1039/c8sc00434j

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